Hidden Roto Symmetries in Nature Discovered

Image Caption: 
Rotation-reversal symmetry operation switches between the orange and aqua molecules that are counter-tilted in the lattice above.
Credits/Names: 

Penn State MRSEC DMR-0820404: Venkatraman Gopalan and D. B. Litvin Rotation-reversal Symmetries in Crystals and Handed Structures Nature Materials, 10, 376 (2011)

MRSEC researchers have discovered a missing spatial operation in nature called rotationreversal symmetry that reverses the sense of all static rotations in a crystal. Certain minerals, organic crystals or metamaterials are composed of subunits that can exist in two states: clockwise or counter-clockwise rotated. The symmetry of a crystal lattice helps determine the material’s properties, and certain properties can only exist in lattices with special symmetries. In perovskite complex oxides, for example, oxygen cages counter-rotate (see image); these crystals have twice as many new “roto” symmetries as previously recognized These new symmetries imply new materials properties: lattice rotation coupled to magnetism, ferroelectricity, multiferroicity, charge ordering, elasticity, and optical. These properties could be useful in electrical control of magnetism, high-speed transistors based on correlated phenomena and high-temperature actuators.

Download PDF Version: 
Year of Research Highlight: 
2011
IRG: 
IRG 1 - Strain-Enabled Multiferroics